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Beilstein J. Org. Chem. 2015, 11, 693–700, doi:10.3762/bjoc.11.79
Graphical Abstract
Scheme 1: Schematic representation of self-sorting effects in metallosupramolecular self-assembly processes.
Scheme 2: Schematic representation of our approach to discrete heteroleptic oligonuclear metallosupramolecula...
Figure 1: Tröger’s base-derived bis(phenanthroline) ligand (rac)-1 and bis(bipyridine) ligand 2.
Scheme 3: Synthesis of chiral bis(phenanthroline) ligand (rac)-1 from 3.
Scheme 4: Synthesis of bis(bipyridine) ligand 2 from 2-aminopyridine (4).
Figure 2: NMR spectra (500.1 MHz in DMSO-d6 at 295 K) of free ligands b) (rac)-1 and c) 2; 1:1 mixtures of li...
Figure 3: ESI mass spectrum (positive ion mode) of a 1:1:2 mixture of (rac)-1, 2, and CuBF4 sprayed from a 10...
Scheme 5: Summary of the coordination behavior of the two ligands 1 and 2 and their equimolar mixture towards...